CONTENIDO DEL LIBRO:
CHAPTER ONE: Primary Raw Materials for Petrochemicals
1.1 Introduction
1.2 Natural Gas
Natural Gas Treatment Processes, Natural Gas Liquids, Properties of Natural Gas
1.3 Crude Oils
Composition of Crude Oils, Properties of Crude Oils, Crude Oil Classification
1.4 Coal, Oil Shale, Tar Sand, and Gas Hydrates
CHAPTER TWO: Hydrocarbon Intermediates
2.1 Introduction
2.2 Paraffinic Hydrocarbons
Methane, Ethane, Propane, Butanes
2.3 Olefinic Hydrocarbons
Ethylene, Propylene, Butylenes
2.4 Dienes
Butadiene, Isoprene
2.5 Aromatic Hydrocarbons
Extraction of Aromatics
2.6 Liquid Petroleum Fractions and Residues
Naphtha, Kerosine, Gas Oil, Residual Fuel Oil
CHAPTER THREE: Crude Oil Processing and Production of Hydrocarbon Intermediates
3.1 Introduction
3.2 Physical Separation Processes
Atmospheric Distillation, Vacuum Distillation, Absorption Process, Adsorption Process, Solvent Extraction
3.3 Conversion Processes
Thermal Conversion Processes, Catalytic Conversion Processes
3.4 Production of Olefins
Steam Cracking of Hydrocarbons, Production of Diolefins
CHAPTER FOUR: Nonhydrocarbon Intermediates
4.1 Introduction
4.2 Hydrogen
4.3 Sulfur
Uses of Sulfur, The Claus Process, Sulfuric Acid
4.4 Carbon Black
The Channel Process, The Furnace Black Process, The Thermal Process, Properties and Uses of Carbon Black
4.5 Synthesis Gas
Uses of Synthesis Gas
4.6 Naphthenic Acids
Uses of Naphthenic Acid and Its Salts
4.7 Cresylic Acid
Uses of Cresylic Acid
CHAPTER FIVE: Chemicals Based on Methane
5.1 Introduction
5.2 Chemicals Based on Direct Reactions of Methane
Carbon Disulfide, Hydrogen Cyanide, Chloromethanes
5.3 Chemicals Based on Synthesis Gas
Ammonia, Methyl Alcohol, Oxo Aldehydes and Alcohols, Ethylene Glycol
CHAPTER SIX: Ethane and Higher Paraffins-Based Chemicals
6.1 Introduction
6.2 Ethane Chemicals
6.3 Propane Chemicals
Oxidation of Propane, Chlorination of Propane, Dehydrogenation of Propane, Nitration of Propane
6.4 n-Butane Chemicals
Oxidation of n-Butane, Aromatics Production, Isomerization of n-Butane
6.5 Isobutane Chemicals
6.6 Naphtha-Based Chemicals
6.7 Chemicals from High Molecular Weight n-Paraffins
Oxidation of Paraffins, Chlorination of n-Paraffins, Sulfonation of n-Paraffins, Fermentation Using n-Paraffins
CHAPTER SEVEN: Chemicals Based on Ethylene
7.1 Introduction
7.2 Oxidation of Ethylene
Derivatives of Ethylene Oxide, Acetaldehyde, Oxidative Carbonylation of Ethylene
7.3 Chlorination of Ethylene
Vinyl Chloride, Perchloro- and Trichloroethylene
7.4 Hydration of Ethylene
7.5 Oligomerization of Ethylene
Alpha Olefins Production, Linear Alcohols, Butene-l
7.6 Alkylation Using Ethylene
CHAPTER EIGHT: Chemicals Based on Propylene
8.1 Introduction
8.2 Oxidation of Propylene
Acrolein, Mechanism of Propene Oxidation, Acrylic Acid, Ammoxidation of Propylene, Propylene Oxide
8.3 Oxyacylation of Propylene
8.4 Chlorination of Propylene
8.5 Hydration of Propylene
Properties and Uses of Isopropanol
8.6 Addition of Organic Acids to Propene
8.7 Hydroformylation of Propylene: The Oxo Reaction
8.8 Disproportionation of Propylene (Metathesis
8.9 Alkylation Using Propylene
CHAPTER NINE: C4 Olefins and Diolefins-Based Chemicals
9.1 Introduction
9.2 Chemicals from n-Butenes
Oxidation of Butenes, Oligomerization of Butenes
9.3 Chemicals from Isobutylene
Oxidation of Isobutylene, Epoxidation of Isobutylene, Addition of Alcohols to Isobutylene, Hydration of Isobutylene, Carbonylation of Isobutylene, Dimerization of Isobutylene
9.4 Chemicals from Butadiene
Adiponitrile, Hexamethylenediamine, Adipic Acid, Butanediol, Chloroprene, Cyclic Oligomers of Butadiene
CHAPTER TEN: Chemicals Based on Benzene, Toluene, and Xylenes
10.1 Introduction
10.2 Reactions and Chemicals of Benzene
Alkylation of Benzene, Chlorination of Benzene, Nitration of Benzene, Oxidation of Benzene, Hydrogenation of Benzene
10.3 Reactions and Chemicals of Toluene
Dealkylation of Toluene, Disproportionation of Toluene, Oxidation of Toluene, Chlorination of Toluene, Nitration of Toluene, Carbonylation of Toluene
10.4 Chemicals from Xylenes
10.5 Terephthalic Acid, Phthalic Anhydride, Isophthalic Acid
CHAPTER ELEVEN: Polymerization
11.1 Introduction
11.2 Monomers, Polymers, and Copolymers
11.3 Polymerization Reactions
Addition Polymerization, Condensation Polymerization, Ring Opening Polymerization
11.4 Polymerization Techniques
11.5 Physical Properties of Polymers
Crystallinity, Melting Point, Viscosity, Molecular Weight, Classification of Polymers
CHAPTER TWELVE: Synthetic Petroleum-Based Polymers
12.1 Introduction
12.2 Thermoplastics
Polyethylene, Polypropylene, Polyvinyl Chloride, Polystyrene, Nylon Resins, Thermoplastic Polyesters, Polycarbonates, Polyether Sulfones, Poly(phenylene) Oxide, Polyacetals
12.3 Thermosetting Plastics
Polyurethanes, Epoxy Resins, Unsaturated Polyesters, Phenol-Formaldehyde Resins, Amino Resins
12.4 Synthetic Rubber
Butadiene Polymers and Copolymers, Nitrile Rubber, Polyisoprene, Polychloroprene, Butyl Rubber, Ethylene Propylene Rubber, Thermoplastic Elastomers
12.5 Synthetic Fibers
Polyester Fibers, Polyamides, Acrylic and Modacrylic Fibers, Carbon Fibers, Polypropylene Fibers
Appendix One: Conversion Factors
Appendix Two: Selected Properties of Hydrogen, Important C1–C10 Paraffins, Methylcyclopentane, and Cyclohexane
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